H302 — Harmful if swallowed

The GHS hazard statement for acute toxicity, oral, category 4. Here is what it means, the label elements that travel with it, and the substances that carry it.

AT A GLANCE · OFFICIAL STATEMENT
“Harmful if swallowed.”
HAZARD CLASS
Acute toxicity, oral
CATEGORY
Category 4
SIGNAL WORD
Warning

What it means

Serious harm — up to and including death — from swallowing a single dose or several doses within 24 hours. Categories 1 (most severe) onward are set from acute toxicity estimates (ATE) per GHS Chapter 3.1.

Precautionary statements paired with H302

When the engine writes SDS Section 2 for a product carrying H302, these are the precautionary statements it assigns, with combined statements written as one line:

Substances that carry H302

1,009 of the 4,228 substances in our database carry H302 when classified in pure form — recognizable examples:

hydrogen peroxide solution
CAS 7722-84-1
formaldehyde
CAS 50-00-0
acetonitrile
CAS 75-05-8
naphthalene
CAS 91-20-3
SAME HAZARD CLASS:H300H301H303

Reference information, not legal or professional advice. Statement texts and allocations follow 29 CFR 1910.1200 Appendix C (the GHS as adopted by OSHA HazCom 2024) as implemented by our classification engine; the regulatory text and agency practice control. Claims last reviewed July 23, 2026.

The engine writes these for you.

When SDS HQ authors an SDS, it assigns the hazard statements, signal word, pictograms, and precautionary statements from these same tables — automatically, with the calculation shown.